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Silylium ions

T. A. Kochina^a, D. V. Vrazhnov^a, E. N. Sinotova^b, M. G. Voronkov<sup>c

a</sup> I. V. Grebenshchikov Institute of Silicate Chemistry of the Russian Academy of Sciences, St. Petersburg
^b St. Petersburg State University, Scientific Research Institute of Chemistry
^c A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences

Abstract: The history and state of the art of research on silylium ions are summarised. Achievements of the last two decades in the preparation of silylium ions as individual species in solutions and crystals and as intermediates in reactions of organosilicon compounds are considered. Attention is focused on ion-molecular reactions of silylium ions with nucleophilic reagents in the gas and condensed phases.

Received: 12.07.2005

DOI: 10.1070/RC2006v075n02ABEH002480

 English version: Russian Chemical Reviews, 2006, 75:2, 95–110

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