This article is cited in 83 papers

Non-metallocene rare-earth organometallic derivatives: synthesis, structure and application in the catalysis of transformations of unsaturated substrates

A. A. Trifonov

G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhnii Novgorod

Abstract: The review summarises advances in the post-metallocene chemistry of rare-earth organometallic compounds. The synthesis, structures and reactivities of complexes containing metal–carbon and metal–hydrogen bonds and stabilised by N-, P- or O-donor ligands are considered. The catalytic activities of these compounds in alkene polymerisation, hydroamination, hydrosilylation and hydroboration are discussed.

Received: 09.01.2007

DOI: 10.1070/RC2007v076n11ABEH003693

 English version: Russian Chemical Reviews, 2007, 76:11, 1051–1072

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