This article is cited in 8 papers

The Influence of Hydrogen Bonds and Ionic Interactions on the Properties of Carboxyl-containing Copolymers and Ionomers Based on Them

N. G. Marina, Yu. B. Monakov, S. R. Rafikov

Institute of Chemistry of the Bashkir Scientific Center, Ural Branch of the USSR, Ufa

Abstract: The changes in the properties of copolymers as a function of the introduction of units with carboxy- and salt groups into the macrochain are examined. Attention is concentrated on the analysis of the results of the study of copolymers in the acid and ionomeric forms in solutions. The decisive influence of ionic interactions on the properties of ionomers in bulk and on their hydrodynamic and conformational characteristics is demonstrated. The difference between hydrogen and ionic bonds in the sense of their effects both on the primary ordering of macromolecules within the chains in copolymers of the types indicated and on the interchain interaction processes is emphasised.
The bibliography includes 163 references.

UDC: 541.64:539.199

DOI: 10.1070/RC1979v048n04ABEH002333

 English version: Russian Chemical Reviews, 1979, 48:4, 389–403

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