This article is cited in 5 papers

Methods of Mathematical Treatment of the Results of Physicochemical Studies on Complex Compounds

E. S. Shcherbakova, I. P. Gol'dshtein, E. N. Gur'yanova

Karpov Institute of Physical Chemistry, Moscow

Abstract: The general principles of the determination of the equilibrium constants and the physicochemical parameters of complexes under the conditions of their dissociation are examined. The possibilities of approximate computational methods and direct analytical procedures for the solution of systems of the corresponding equations are analysed. Various methods involving the simultaneous determination of the equilibrium constants and physicochemical parameters of complexes, based on the statistical principle of maximum probability, are compared. The ways of the most rational employment of computer techniques in the study of involved complex-formation reactions by various physical methods are discussed.
The bibliography includes 226 references.

UDC: 541.49

DOI: 10.1070/RC1978v047n12ABEH002297

 English version: Russian Chemical Reviews, 1978, 47:12, 1133–1148

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