This article is cited in 10 papers

The Structure and Reactivity of Phosphorus Pentachloride

S. V. Fridland, B. D. Chernokal'skii

Kazan Institute for Chemical Technology

Abstract: Data are presented on the reactions of phosphorus pentachloride with compounds containing oxa- and oxy-groups (ethers, acetals, oxetans, tetrahydrofuran, 1,3-dioxans, dioxolans, dihydropyrans, and alcohols). The structure of phosphorus pentachloride in various solvents and its influence on the course of reactions are considered. The mechanisms proposed for the reactions under discussion are analysed.
The bibliography includes 119 references.

UDC: 547.241.547.313

DOI: 10.1070/RC1978v047n08ABEH002257

 English version: Russian Chemical Reviews, 1978, 47:8, 742–750

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