This article is cited in 38 papers

Solid-phase Radical Reactions and Mechanism of Oxidation of Carbon-chain Polymers

E. T. Denisov

Chernogolovka Institute of Chemical Physics of the USSR Academy of Sciences

Abstract: Analysis of recent results on the kinetics of the oxidation of model hydrocarbons and carbon-chain polymers in solution and in the solid phase emphasises the common character of the oxidation mechanisms in liquid and solid phases. Detailed consideration is given to specific features of the solid-phase oxidation of polymers consequent on their high molecular mass, inhomogeneity in the solid state, the influence of molecular mobility on the kinetics of radical reactions, and the migration of free electrons. A list of 104 references is included.

UDC: 541.515

DOI: 10.1070/RC1978v047n06ABEH002239

 English version: Russian Chemical Reviews, 1978, 47:6, 572–586

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