This article is cited in 15 papers

The Reactivity of Carbanions

A. A. Solov'yanov, I. P. Beletskaya

Lomonosov Moscow State University, Faculty of Chemistry

Abstract: Ionic species involved in the reactions of alkali and alkaline-earth metal salts of CH-acids with various electrophiles are discussed, as well as the factors influencing the relative concentrations of these species. The reactivities of carbanions and their ion-pairs in nucleophilic substitution and addition and in electron and proton transfers are examined in terms of quantitative experimental results. A list of 140 references is included.

UDC: 547.16

DOI: 10.1070/RC1978v047n05ABEH002228

 English version: Russian Chemical Reviews, 1978, 47:5, 425–439

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