This article is cited in 24 papers

Electron Diffraction Studies on Stereochemically Non-rigid Molecules

V. P. Spiridonov, A. A. Ischenko, E. Z. Zasorin

Lomonosov Moscow State University, Faculty of Chemistry

Abstract: Electron diffraction data for the structures and potential energy functions of molecules with a certain type of intramolecular motion – high-amplitude motion – are analysed in detail and the fundamental characteristics of such motion and the conditions for its experimental observation are formulated. Important structural-chemical consequences of high-amplitude motion and the urgent need for a comprehensive investigation of stereochemically non-rigid molecules are demonstrated.
The bibliography includes 201 references.

UDC: 539.27

DOI: 10.1070/RC1978v047n01ABEH002203

 English version: Russian Chemical Reviews, 1978, 47:1, 54–68

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