This article is cited in 1 paper

Theory of Complex Unimolecular Reactions

A. D. Berman

Institute of Chemical Physics of the USSR Academy of Sciences, Moscow

Abstract: A general approach to the study of complex reacting systems, including first-order reactions, is considered. The method consists in the identification of the disposition of the characteristic vectors of the kinetic matrix for a linear system and their eigenvalues. Linear reaction pathways in the composition space correspond to non-equilibrium characteristic vectors. For an experimental determination of the kinetic constants in a complex system, it is sufficient to find all the linear reaction pathways.
The bibliography includes 56 references.

UDC: 541.124/128

DOI: 10.1070/RC1976v045n11ABEH002748

 English version: Russian Chemical Reviews, 1976, 45:11, 983–1007

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