This article is cited in 40 papers

Fluorinated Ketenimines

N. P. Gambaryan

A. N. Nesmeyanov Institute of Organoelement Compounds, USSR Academy of Sciences, Moscow

Abstract: Methods of obtaining imines of fluorinated ketens are surveyed, together with their dimerisation and nucleophilic addition. Cycloaddition at the carbon–nitrogen bond and 1,4-dipolar cycloaddition involving the aromatic ring are most characteristic of fluorine-containing N-arylketenimines. A two-stage mechanism is suggested, involving intermediate formation of small rings.
The Review concludes with 92 references.

UDC: 547.446.8

DOI: 10.1070/RC1976v045n07ABEH002698

 English version: Russian Chemical Reviews, 1976, 45:7, 630–638

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