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JOURNALS // Uspekhi Khimii // Archive

Usp. Khim., 1976 Volume 45, Issue 5, Pages 908–937 (Mi rcr2891)

This article is cited in 65 papers

Nucleophilic Substitution of Hydrogen in Aromatic Systems

O. N. Chupakhin, I. Ya. Postovskii

Ural State Technical University, Sverdlovsk

Abstract: The literature data on the substitution of hydrogen under the influence of nucleophilic agents in aromatic and heteroaromatic systems and in quinones are reviewed. The absence of an ionic stabilisation of the hydrogen substituted with its pair of binding electrons is responsible for the specific nature of the reactions under consideration, which is different from that of the nucleophilic substitution of other species and from that of the electrophilic substitution of hydrogen, necessitating the use of an oxidant in most instances.
The bibliography includes 227 references.

UDC: 547.52+542.942.7

DOI: 10.1070/RC1976v045n05ABEH002670


 English version:
Russian Chemical Reviews, 1976, 45:5, 454–468

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