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Chalcogenide clusters of Group 5–7 metals

V. E. Fedorov, Yu. V. Mironov, N. G. Naumov, M. N. Sokolov, V. P. Fedin

Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk

Abstract: The state-of-the-art and prospects of the development of chemistry of chalcogenide clusters of Group 5–7 metals of the Periodic Table are discussed. The main structural types, methods of synthesis, the reactivity and possible applications of vanadium, niobium, tantalum, chromium, molybdenum, tungsten and rhenium chalcogenide clusters with nuclearity of three and larger are considered.

Received: 02.04.2007

DOI: 10.1070/RC2007v076n06ABEH003707

 English version: Russian Chemical Reviews, 2007, 76:6, 529–552

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