This article is cited in 16 papers

Ions and Ion-pairs in Nucleophilic Aliphatic Substitution

I. P. Beletskaya

Lomonosov Moscow State University

Abstract: A survey is made of the involvement of ions and ion-pairs formed both by the nucleophilic reagent and by the substrate. Evidence is given for the existence of ion-pairs of different types (contact and solvent-separated) in S_N1 reactions, and the possible participation of the former type in S_N2 processes is examined.
A list of 338 references is included.

UDC: 547.171:547.211+547.31

DOI: 10.1070/RC1975v044n12ABEH002558

 English version: Russian Chemical Reviews, 1975, 44:12, 1067–1090

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