This article is cited in 34 papers

Advances in the Chemistry of Triptycene

V. R. Skvarchenko^a, V. K. Shalaev^a, E. I. Klabunovskii<sup>b

a</sup> Lomonosov Moscow State University, Faculty of Chemistry
^b N. D. Zelinskii Institute of Organic Chemistry of the USSR Academy of Sciences, Moscow

Abstract: Information is presented on the preparation of triptycene, its homologues, and substituted derivatives. The spectroscopic, X-ray, optical, and other physical properties of these compounds are discussed. A systematic account is given of the behaviour of substituents located at a bridgehead, and of the differing reactivities of α- and β-positions in the aromatic rings on nucleophilic and electrophilic substitution. Reactions involving opening of the bridge system, the polarographic reduction of triptycenequinones, and the catalytic hydrogenation of triptycene are considered.
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UDC: 547.674

DOI: 10.1070/RC1974v043n11ABEH001875

 English version: Russian Chemical Reviews, 1974, 43:11, 951–966

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