This article is cited in 16 papers

Vibration Spectra and Structures of the Simplest Aromatic Derivatives of Group I–VI Elements

A. N. Rodionov

Karpov Institute of Physical Chemistry, Moscow

Abstract: The review gives a general and systematic account of experimental and calculated data on the vibration spectra and structures of the simplest aromatic derivatives of non-transition Group I–VI elements. Particular attention has been devoted to "M-sensitive" vibrations, i.e. vibrations involving the element M, the frequencies of the corresponding bands, their activites, and the splittings of the components as a function of molecular structure. The monosubstituted benzene approximation is shown to have poor suitability for the interpretation of the spectra of derivatives of polyvalent elements. The bibliography includes 145 references.

UDC: 543.42+547.40-2

DOI: 10.1070/RC1973v042n12ABEH002780

 English version: Russian Chemical Reviews, 1973, 42:12, 998–1010

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