This article is cited in 4 papers

Intramolecular Rearrangements of Hydrocarbon Radicals in the Gas Phase

A. D. Stepukhovich, V. I. Babayan


Abstract: The review deals with the rearrangements of alkyl radicals occurring in various gas-phase processes. Intramolecular isomerisations involving the migration of a hydrogen atom with formation of three-, four-, five-, and six-membered transition states are examined. The possibility of the isomerisation of small alkyl radicals (ethyl and propyl radicals) and of the transfer of hydrogen to a neighbouring carbon atom in long-chain radicals is discussed. The process mechanism is considered. The bibliography includes 82 references.

DOI: 10.1070/RC1972v041n09ABEH002090

 English version: Russian Chemical Reviews, 1972, 41:9, 750–758

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