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JOURNALS // Uspekhi Khimii // Archive

Usp. Khim., 1972 Volume 41, Issue 5, Pages 828–851 (Mi rcr2533)

This article is cited in 35 papers

Effect of dπpπ Interaction in Organic Compounds of Group IVB Elements

A. N. Egorochkin, N. S. Vyazankin, S. Ya. Khorshev

Institute of Chemistry, Academy of Sciences of the USSR, Gor'kii

Abstract: The behaviour of organic derivatives of Group IVB elements is markedly influenced by dπpπ interaction in the ground and excited states. Chemical and physical techniques are nowadays widely used to investigate dπpπ interaction. This review deals with the results of certain spectroscopic (NMR and infrared) studies on this effect. The experimental data obtained by NMR and infrared spectroscopy have been compared in a number of cases with the results obtained by other research techniques. The bibliography includes 222 references.

UDC: 547:13:541.67:541.651

DOI: 10.1070/RC1972v041n05ABEH002065


 English version:
Russian Chemical Reviews, 1972, 41:5, 425–438

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