This article is cited in 30 papers

Mechanisms of reactions of organoaluminium compounds with alkenes and alkynes catalyzed by Zr complexes

L. V. Parfenova, L. M. Khalilov, U. M. Dzhemilev

Institute of Petrochemistry and Catalysis of RAS, Ufa

Abstract: The results of studies dealing with mechanisms of hydro-, carbo- and cycloalumination of alkenes and alkynes catalyzed by zirconium complexes are generalized and systematized for the first time. Data about the structures of intermediates responsible for the formation of the target compounds are presented and the available data on the effect of the structure of organoaluminium compounds and the electronic and steric factors determining the catalytic activity of metal complexes in these reactions are considered in detail. Much attention is paid to studies of the influence of reaction conditions on the chemo-, regio- and stereoselectivity of the Zr-containing complex catalysts. The bibliography includes 217 references.

Received: 17.05.2011

DOI: 10.1070/RC2012v081n06ABEH004225

 English version: Russian Chemical Reviews, 2012, 81:6, 524–548

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