This article is cited in 9 papers

The Structure of Aliphatic Diazo-compounds and Their Isomers

O. P. Studzinskii, I. K. Korobitsyna

Leningrad State University

Abstract: The review describes the modern concepts concerning the electronic fine structure of aliphatic diazo-compounds based on experimental data (from infrared, ultraviolet, and PMR spectroscopy) and also quantum-mechanical calculations by the LCAO-MO method. These concepts explain many chemical properties of diazoalkanes and sometimes make it possible to predict them. Apart from "classical" aliphatic diazo-compounds, the structures and properties of the isomers – linear (N-isocyanamine) and cyclic (diazirines) – are considered.
The bibliography comprises 99 references.

UDC: 547.02:547.235:547.717:543.422

DOI: 10.1070/RC1970v039n10ABEH002046

 English version: Russian Chemical Reviews, 1970, 39:10, 834–843

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