This article is cited in 30 papers

Effect of a Solid Surface on Relaxation and Structure-formation Processes in Polymer Layers Adjoining the Walls

Yu. M. Malinskii


Abstract: Data on the characteristic properties, in particular crystallisation properties, of low-molecular substances in layers adjoining the walls are briefly discussed. The methods for and the results of the determinations of the thickness of wall layers of solutions and melts of many polymers are quoted. Data on the effect of a solid surface on the rate of relaxation processes and the properties of the polymers due to them are reviewed.
The effect of artificial nucleating agents on the structure (and properties) of polymers, the suppression of structure formation in thin layers in certain systems, and epitaxy are discussed.
The experimental data presented are treated from the standpoint of the hypothesis of the packet structure of polymers and the effect of the interaction between the solid surface and the polymer on the enthalpy and entropy of the system.
The bibliography includes 232 references.

DOI: 10.1070/RC1970v039n08ABEH002017

 English version: Russian Chemical Reviews, 1970, 39:8, 704–718

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