This article is cited in 15 papers

Dynamic and stimulated nuclear polarisation in photochemical radical reactions

E. G. Bagryanskaya, R. Z. Sagdeev

International Tomography Center of the Siberian Branch of the Russian Academy of Sciences, Novosibirsk

Abstract: Highly sensitive time-resolved magnetic resonance techniques based on the effect of variable radio-frequency and switched constant magnetic fields on the nuclear polarisation of diamagnetic products of radical reactions are considered. The applications of these methods to the investigation of short-lived radical intermediates (radical pairs, biradicals, free radicals and radical ions) formed in photochemical reactions in homogeneous and molecular-organised media are discussed. The bibliography includes 148 references.

UDC: 541.18+541.6

Received: 25.04.2000

DOI: 10.1070/RC2000v069n11ABEH000599

 English version: Russian Chemical Reviews, 2000, 69:11, 925–945

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