This article is cited in 52 papers

Types of cationic complexes based on oxocentred tetrahedra [OM₄] in the crystal structures of inorganic compounds

S. V. Krivovichev, S. K. Filatov, T. F. Semenova

Department of Crystallography, St.-Petersburg State University

Abstract: The crystal structures of inorganic compounds comprising cationic complexes containing oxygen atoms coordinated tetrahedrally to metal atoms, or oxocentred groups [OM₄], are considered. The linking of the [OM₄] tetrahedra in the structures has been analysed and cationic complexes of different structures have been identified. The rules governing the linking of the [OM₄] tetrahedra have been formulated and the cationic complexes have been subjected to a detailed systematic treatment on their basis. Data on the statistics of the bond lengths and bond angles in the [OM₄] tetrahedra are presented. The bibliography includes 317 references.

UDC: 548.736

Received: 11.09.1997

DOI: 10.1070/RC1998v067n02ABEH000287

 English version: Russian Chemical Reviews, 1998, 67:2, 137–155

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