This article is cited in 6 papers

The nuclear-spin selectivity of chemical reactions

A. L. Buchachenko

N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, Moscow

Abstract: The ability of spin-selective chemical reactions to sort nuclei in terms of two features – their spin and orientation – is discussed. The subdivision into spin (magnetic) and spin-free (nonmagnetic) nuclei constitutes the basis of the magnetic isotope effect; the subdivision of nuclei in terms of orientations and the establishment of the nuclear orientation constitute the content of second phenomenon – chemically induced [dynamic] nuclear polarisation. The bibliography includes 50 references.

UDC: 541.139

Received: 14.02.1995

DOI: 10.1070/RC1995v064n09ABEH000177

 English version: Russian Chemical Reviews, 1995, 64:9, 809–816

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