This article is cited in 12 papers

Photochemical reactions of complexes of aromatic amines with polygalomethanes

M. F. Budyka^a, M. V. Alfimov<sup>b

a</sup> Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow region
^b N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, Moscow

Abstract: Data concerning the chemical processes occurring under light irradiation of complexes of aromatic amines with polyhalomethanes are critically reviewed. It is shown that electron transfer from an amine to a halomethane is the main photochemical reaction of the complexes. The properties and reactions of primary radical-ion species and secondary inter-mediates formed are discussed. The mechanisms of photo-induced formation of triphenylmethane dyes and acridine derivatives are considered in detail. The bibliography includes 234 references.

UDC: 541.14

Received: 06.03.1995

DOI: 10.1070/RC1995v064n08ABEH000170

 English version: Russian Chemical Reviews, 1995, 64:8, 705–717

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