N. Ya. Grigorieva, O. A. Pinsker, “New methods of synthesis of linear functionalised (<i>Z</i>)-isoprenoids and their 2,3-dihydro-derivatives”, Usp. Khim., 1994, Volume 63, Issue 2,Pages <nobr>177

This article is cited in 6 papers

New methods of synthesis of linear functionalised (Z)-isoprenoids and their 2,3-dihydro-derivatives

N. Ya. Grigorieva, O. A. Pinsker

N. D. Zelinskii Institute of Organic Chemistry, Moscow

Abstract: The chemical and microbiological methods developed for the synthesis of polyprenols and dolichols are examined. These methods involve the construction of regular functionalised (Z)-isoprenoids accompanied by the creation of new C–C and/or (Z)-trisubstituted C=C bonds. Also considered are the highly regioselective and enantioselective procedures for the conversion of α-functionalised isoprenoids into their 2,3-dihydro-derivatives. The bibliography includes 87 references.

UDC: 541.63:542.91:541.64:547.366

Received: 01.12.1993

DOI: 10.1070/RC1994v063n02ABEH000078