This article is cited in 16 papers

Coordination-radical (co)polymerisation of vinyl monomers in the presence of organic compounds of Group III–V elements

D. F. Grishin

N. I. Lobachevski State University of Nizhni Novgorod

Abstract: The influence of catalytic amounts of organic compounds of Group III–V elements on the initiation stage and chain propagationd in the (co)polymerisation of vinyl and certain other monomers is discussed. The question concerning the formation of complexes by the monomers and growth radicals with organoelement additives are examined. Examples of the practical application of the coordination-radical (co)polymerisation with participation of organic compounds of Group III–V elements, including peroxides, in the synthesis of high-molecular-mass substances, including the copolymers of vinyl monomers and olefins as well as alternating copolymers based on acrylates, are presented. The bibliography includes 105 references.

UDC: 541.64:547.1'13:678.044

Received: 01.02.1993

DOI: 10.1070/RC1993v062n10ABEH000056

 English version: Russian Chemical Reviews, 1993, 62:10, 951–962

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