This article is cited in 26 papers

Structural features and spectroscopic and energy characteristics of alkali metal molybdates and tungstates

V. V. Fomichev, M. È. Poloznikova, O. I. Kondratov

Moscow Institute of Fine Chemical Technology

Abstract: The results of X-ray structural, IR and Raman spectroscopic, and thermodynamic studies of alkali metal molybdates and tungstates A₂M_nO_3n+1 (A = Li, Na, K, Rb, Cs; M = Mo, W) are reviewed and analysed. The dependence of the vibrational spectra, activation energies, and crystal lattice energies on features of the structures of these compounds is discussed. The bibliography includes 51 references.

UDC: 535.34:543.424:536.7:546.776'311.786'311

Received: 23.04.1992

DOI: 10.1070/RC1992v061n09ABEH001004

 English version: Russian Chemical Reviews, 1992, 61:9, 877–888

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