This article is cited in 15 papers

Stereoelectronic effects in silicon, phosphorus, and sulfur molecules. Quantum-chemical calculations and qualitative orbital models

A. A. Korkin

Institute of Physiologically Active Compounds RAS, Chernogolovka

Abstract: The results of non-empirical quantum-chemical calculations for silicon, phosphorus, and sulfur compounds of different structure are discussed. Qualitative orbital models, which establish a relation between the distribution of electrons and molecular structure and properties, are analysed. A general definition of stereoelectronic effects is presented. The bibliography includes 176 references.

UDC: 541.5

DOI: 10.1070/RC1992v061n05ABEH000957

 English version: Russian Chemical Reviews, 1992, 61:5, 473–483

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