This article is cited in 6 papers

Reactions of phosphorus-containing compounds with diazo-compounds and carbenes

B. A. Khaskin, O. D. Molodova, N. A. Torgasheva

All-Union Research Institute of Plant Protection Chemicals, Moscow

Abstract: The reactions of various phosphorus-containing systems with diazo-compounds and carbenes are presented for the first time in a general form and a systematic account is given of literature data on the reactivities of phosphorus-containing acids, salts, esters, amides, sulphenamides, phosphorus acid sulphenyl halides, phosphorus halides, and derivatives of mono-, di-, and tri-coordinate phosphorus in reactions with diazo-compounds and carbenes. The differences between the reactivities of diazo-compounds and carbenes in relation to the above groups of organophosphorus compounds are demonstrated. The bibliography includes 244 references.

UDC: 547.26'118

DOI: 10.1070/RC1992v061n03ABEH000947

 English version: Russian Chemical Reviews, 1992, 61:3, 306–334

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