Abstract:
We have studied the formation and modification of germanium nanoclusters in GeO$_x$ films under the action of pulse laser and isochronous furnace annealing. Pulse treatments were effected using either a Tisapphire laser operating at a wavelength of $\lambda$ = 800 nm and a pulse duration $\tau$ of about 30 fs or a KrF excimer laser with $\lambda$ = 248 nm and $\tau$ = 25 ns. The pulse annealing stimulated both the crystallization of initial amorphous Ge nanoclusters in GeO$_x$ matrix and the formation of new nanoclusters. In order to prevent the evaporation of films under the action of laser radiation, the samples were covered with a protective layer of SiN$_x$O$_y$. The proposed approach can be used for the modification of dimensions and phase composition of Ge clusters in GeO$_x$ films.