Formation of thin nanostructured layers during heterogeneous gas-phase synthesis from small-size volatile metal complexes on the surface of semiconductors and dielectrics
Abstract:
We have developed and verified a new method for the formation of thin nanostructured layers on semiconductor and dielectric substrates by heterogeneous gas-phase synthesis from small-sized volatile metal complexes. Thin nanostructured layers of copper on silicon and silica substrates were successfully formed from small-sized volatile formiate metal complexes using a combined synthesis-transfer process. It is established that copper in the layers deposited by this method predominantly occurs in the metallic (Cu$^0$) state in nanosized grains with a characteristic close-packed structure.