Abstract:
BiTeI and BiTeBr single crystals are synthesized by the Bridgman method, and their galvanomagnetic and thermoelectrical properties are investigated. Both semiconductors have $n$-type conductivity. The thermoelectric efficiency of BiTeBr is much higher than that of BiTeI, which is related mainly to a larger See-beck coefficient for the former compound. For both crystals, the band structure is calculated from the density-functional theory. It is shown that both compounds are semiconductors with an indirect energy band gap.