Abstract:
The method of confocal Raman microscopy is used for the first time to study the spatial distribution of elemental composition and elastic strains in self-assembled Ge$_x$Si$_{1-x}$/Si(001) islands grown by the method of sublimation molecular-beam epitaxy in the GeH$_4$ ambient. The lines related to vibrational modes Si–Si, Ge–Ge, and Si–Ge are identified in the Raman spectra measured in the regions with dimensions $<$ 100 nm on the surface of the samples. The spatial distribution of the Ge atomic fraction $x$ in the Ge$_x$Si$_{1-x}$ alloy and of the elastic strain $\varepsilon$ (averaged in depth over the island layer) have been calculated from the maps of the Raman shifts of the corresponding lines over the sample surface. The dependences of $x$ and $\varepsilon$ on the islands’ growth temperature and on the nominal thickness of the deposited Ge layer have been studied.