Abstract:
Sets of fundamental optical functions in the energy range of 0–40 eV for longitudinal indirect interband transitions in graphite with a quasi-gap up to 2.6 eV have been determined for the first time. Their structure and parameters depend strongly on the electron wave vector transfer
$\mathbf{q}$. The nature of the peaks and shoulders of these functions is explained within the model of theoretical shifted bands for four electron wave vector transfers $\mathbf{q}$ in a volume characteristic electron-energy losses for the $\Gamma$–$P$ direction in the Brillouin zone. The calculations were performed on the basis of the known experimental volume characteristic electron-energy loss spectra of graphite in the range of 0–40 eV for $|\mathbf{q}|$ = 0.00, 0.375, 0.625, and 1.00 $\mathring{\mathrm{A}}^{-1}$ using a special software package.