Abstract:
The temperature dependences of electrical conductivity $\sigma(T)$ and the Hall coefficient $R(T)$ in Ag$_2$S at the phase transition have been studied. Qualitative discrepancies in the changes in $\sigma(T)$ and $R(T)$ in the case of phase transition have been revealed; i.e., $\sigma$ increases by several orders of magnitude while $R$ decreases by a factor of 3–4. This is interpreted in the context of a model with two types of charge carriers and with variation in the band parameters and the concentration of defects formed at the phase transition taken into account.