Abstract:
The Mg$_x$Zn$_{1-x}$O thin films with a Mg content corresponding to $x$ = 0–0.45 are grown by pulsed laser deposition on ablation of ceramic targets. The conditions for epitaxial growth of the films on the single-crystal Al$_2$O$_3$ (00.1) substrates are established. The record limit of solubility of Mg in hexagonal ZnO, $x$ = 35 is attained. In this case, the lattice mismatch for the parameter a of the ZnO and Mg$_{0.35}$Zn$_{0.65}$O films does not exceed 1%, whereas the band gaps of the films differ by 0.78 eV. The surface roughness of the films corresponds to 0.8–1.5 nm in the range of $x$ = 0–0.27.