Abstract:
It is shown that a study of the dependence of impurity-related resonant first-order Raman scattering on the frequency of excitation light makes it possible to observe the dispersion of polar optical and acoustic branches of vibrational spectrum in hexagonal InN within a wide range of wave vectors. It is established that the wave vectors of excited phonons are uniquely related to the energy of excitation photon. Frequencies of longitudinal optical phonons $E_1$(LO) and $A_1$(LO) in hexagonal InN were measured in the range of excitation-photon energies from 2.81 to 1.17 eV and the frequencies of longitudinal acoustic phonons were measured in the range 2.81–1.83 eV of excitation-photon energies. The obtained dependences made it possible to extrapolate the dispersion of phonons $A_1$(LO) è $E_1$(LO) to as far as the point $\Gamma$ in the Brillouin zone and estimate the center-band energies of these phonons (these energies have not been uniquely determined so far).