Abstract:
Profiles of impurity distribution and spreading resistance have been studied in the layers of ferromagnetic silicon obtained by implantation of Mn (or Co). Standard wafers of $n$- and $p$-Si with a high or low electrical conductivity were implanted with Mn ions with the dose (1–5) $\cdot$ 10$^{16}$ cm$^{-2}$. It is found that, as a result of postimplantation annealing in vacuum for 5 min at 850$^\circ$C, Mn manifests itself as an amphoteric impurity and compensates acceptors in high-resistivity $p$-Si and donors in low-resistivity $n$-Si. It is shown that only an insignificant fraction of Mn ions (1–2%) is electrically active and is involved in compensation. The magnitude of compensation is used to determine energies of the levels $E_c$ – 0.12 eV for $n$-Si and $E_v$ + 0.32 eV for $p$-Si; these levels are attributed to Mn ions at interstitial sites in the silicon crystal lattice, i.e., (Mn$_i$)$^{-/0}$ è (Mn$_i$)$^{+/++}$, respectively.