Abstract:
The effect of tin impurity on the structure and optical properties of thin-film amorphous silicon is investigated. It is established that tin impurity accelerates crystallization of amorphous silicon. Immediately after deposition of a film onto a substrate at a temperature of $\sim$300$^\circ$C, there is a crystalline phase of silicon in samples with tin. High-vacuum annealing at 350–750$^\circ$C leads to growth of the crystalline phase in films with tin: nanocrystals grow in size from $\sim$3.0 to 4.5 nm. At the same time, in films without tin, only the degree of the short-range order increases. Silicon film without tin remains amorphous over the entire range of annealing temperatures.