Abstract:
The effect of microwave radiation on the transformation of impurity-based structural complexes in CdTe:Cl single crystals is studied using low-temperature photoluminescence measurements. It is shown that microwave radiation activates Cl$_{\mathrm{Te}}$ centers, resulting in an increase in the intensity of photoluminescence line of excitons bound at the corresponding Cl$_{\mathrm{Te}}$ donor centers. A nonmonotonic dependence of the integrated photoluminescence intensity on the duration of microwave irradiation is observed. At the initial stage of microwave irradiation ($t$ = 30 s), an increase in the integrated excitonic photoluminescence intensity is observed; as the duration of microwave irradiation is increased, the photoluminescence intensity decreases. The experimentally observed variations in the photoluminescence intensity are athermal in nature. The hypothetical mechanism of transformation of impurity-based structural complexes is described.