Abstract:
Crystals of the ternary compound FeIn$_2$S$_4$ are grown by directional crystallization of a melt (the horizontal Bridgman method). Composition of the crystals and their crystal structure are determined. Magnetic properties of the FeIn$_2$S$_4$ crystals are studied in the temperature range 4–310 K in magnetic fields of 0–140 kOe. It is shown that the crystals under study are paramagnets up to $\sim$12 K and their specific magnetic moment monotonically increases with decreasing temperature. The antiferromagnetic character of indirect interactions between Fe$^{2+}$ cations is established. The most probable causes and the mechanism of the formation of the magnetic state in the FeIn$_2$S$_4$ crystals are discussed.