Abstract:
A new ternary compound is synthesized for the first time, and bulk CuIn$_5$Te$_8$ single crystals are grown by directed crystallization of near-stoichiometric melt. It is established from X-ray diffraction patterns of grown crystals that they exhibit the structure of imperfect chalcopyrite with parameters of the unit cell of CuIn$_5$Te$_8$, which were close to those known for the CuInTe$_2$ ternary compound with the composition index $n$ = 0. First, photosensitive structures are fabricated based on CuIn$_5$Te$_8$ crystals, and photosensitivity spectra are obtained for them; it is shown that it is possible to achieve broadband photosensitivity under illumination of the barrier side of these crystals. From the analysis of photosensitivity spectra, the character of band-to-band transitions and corresponding energies of these transitions in CuIn$_5$Te$_8$ are determined. This opens up prospects to use this new semiconductor in photoconverters of solar radiation.