Abstract:
The dependence of the absorption coefficient on incident photon energy in a MnGa$_2$Se$_4$ single crystal has been investigated in the temperature range 110–295 K. Using group-theory analysis of the electron state symmetry and comparison of the symmetry of the energy spectrum of MnGa$_2$Se$_4$ and its isoelectronic analogs, a conclusion about the character of optical transitions has been drawn. It is shown that the features observed at 2.31 and 2.45 eV are related to the intracenter transitions $^6A_1^1\to^4T_2(^4G)$ and $^6A_1^2\to^4T_2(^4G)$. The $^6A_1$ state is split by the crystal field.