Abstract:
The effect of tin on the formation and annealing of radiation defects in $p$-type germanium crystals irradiated with 6-MeV electrons at a temperature of 80 K is studied. It is shown that acceptor complexes SnV with a hole ionization enthalpy of 0.16 eV are dominant in irradiated Ge:(Sn, Ga) crystals after their heating to a temperature of 300 K. These complexes disappeared as a result of the annealing of irradiated crystals in the temperature range 30–75$^\circ$C. Annealing of irradiated crystals at temperatures in the range 110–150$^\circ$C brings about the formation of deep-level centers with a donor level at $E_v$ + 0.29 eV; this center is presumably related to a complex consisting of a tin atom and an interstitial gallium atom.