Abstract:
Chalcogenide alloys in the Ge–Sb–Te system are promising for application in phase-change memory devices. We investigated the influence of bismuth on the optical properties of Ge$_2$Sb$_2$Te$_5$ thin films and established that the bismuth doping in them allows the optical contrast of the thin films to be increased by about 30% at a wavelength of 400 nm. The experimental results are explained in an assumption on the impurity substitution of bismuth for antimony.