Abstract:
The photoluminescence and photoluminescence excitation spectra of SiO$_2$ films implanted with high (3 at%) Si+-ion doses are studied in relation to the temperature of postimplantation annealing. It is shown that two photoluminescence bands with peaks at 2.7 and 2 eV are dominant in the spectra. As the annealing temperature is increased, the relation between the intensities of the 2.7 and 2 eV bands changes in favor of the former one. Both of the photoluminescence bands have their main excitation peak at the energy 5.1 eV. The excitation spectrum of the $\sim$ 2-eV band exhibits also peaks at 3.8 and 4.6 eV. It is concluded that, in the implanted SiO$_2$ films, the orange photoluminescence band originates from radiative transitions between levels of centers associated with a deficiency of oxygen ($\equiv$ Si–Si $\equiv$ or =Si:) and the levels of nonbridging oxygen ($\equiv$ Si–O$\bullet$).