Abstract:
The results of studying dielectric relaxation processes in the Ge$_{28.5}$Ðb$_{15}$S$_{56.5}$ glassy system are presented. The existence of the non-Debye relaxation process caused by the distribution of relaxors over the relaxation time according to the Cole–Cole model is revealed. The energy and structural parameters are calculated: the activation energy $E_p$ = 0.40 eV and the molecular dipole moment $\mu$ = 1.08 D. The detected features are explained within the model according to which the chalcogenide-glass structure is a set of dipoles formed by charged defects such as $D^+$ and $D^-$.