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JOURNALS // Problemy Fiziki, Matematiki i Tekhniki (Problems of Physics, Mathematics and Technics) // Archive

PFMT, 2025 Issue 4(65), Pages 56–61 (Mi pfmt1064)

PHYSICS

Gas-phase synthesis, molecular structure of multilayer coatings based on polypyrrole

M. A. Yarmolenko, A. V. Rogachev, A. A. Rogachev

Francisk Skorina Gomel State University

Abstract: The molecular structure, morphology, and electrical conductivity of polypyrrole coatings deposited on an iron chloride sublayer were determined. The changes in the molecular structure and electrical conductivity during heat treatment of the synthesized polypyrrole layers were established. To effectively mitigate the degradation of polypyrrole coatings during heating, the formation of a sulfate or phosphate passivation layer on their surface was proposed. The decrease in conductivity during heat treatment and the increase in the threshold voltage, above which a conductivity increase is observed, during storage are attributed to the chemical interaction between the copper electrode and iron chloride.

Keywords: polypyrrole coatings, molecular structure, electrical conductivity, morphology, heat treatment.

UDC: 539.23:541.64.052

Received: 19.09.2025

DOI: 10.54341/20778708_2025_4_65_56



© Steklov Math. Inst. of RAS, 2026