N. A. Tarasova, A. O. Galisheva, I. E. Animitsa, “The local structure and hydration processes of halogen-substituted perovskites based on Ba$_{4}$In$_{2}$Zr$_{2}$O$_{11}$”, Optics and Spectroscopy, 2019, Volume 126, Issue 4,Pages 419

This article is cited in 1 paper

Spectroscopy of condensed matter

The local structure and hydration processes of halogen-substituted perovskites based on Ba$_{4}$In$_{2}$Zr$_{2}$O$_{11}$

N. A. Tarasova, A. O. Galisheva, I. E. Animitsa

Institute of Natural Sciences and Mathematics, Ural Federal University Named after the First President of Russia B.N. Yeltsin, Yekaterinburg, Russia

Abstract: Halogen-substituted perovskites Ba$_{4}$In$_{2}$Zr$_{2}$O$_{10.95}$F$_{0.1}$ and Ba$_{4}$In$_{2}$Zr$_{2}$O$_{10.95}$Cl$_{0.1}$ are synthesized, and their single-phase composition is verified by X-ray diffraction analysis. Their ability of the studied phases to hydrate and form energetically unequal OH$^-$ groups is proved. It is found that introduction of halide ions leads to a decrease in the hydration degree with respect to the matrix composition, which is explained by a decrease in the crystal unit cell free volume Processes.

Received: 03.09.2018
Revised: 03.09.2018
Accepted: 11.12.2018

DOI: 10.21883/OS.2019.04.47509.266-18