E. V. Fedorenko, A. A. Khrebtov, A. G. Mirochnik, P. S. Nefedov, L. A. Lim, V. A. Reutov, I. S. Pavlov, A. A. Sergeev, “Effect of polymer matrix on the luminescent properties of compositions doped with boron chelates”, Optics and Spectroscopy, 2019, Volume 127, Issue 3,Pages <nobr>425

This article is cited in 13 papers

Spectroscopy of condensed matter

Effect of polymer matrix on the luminescent properties of compositions doped with boron chelates

E. V. Fedorenko^a, A. A. Khrebtov^b, A. G. Mirochnik^a, P. S. Nefedov^b, L. A. Lim^b, V. A. Reutov^b, I. S. Pavlov^b, A. A. Sergeev^c

^a Institute of Chemistry, Far East Branch of the Russian Academy of Sciences, Vladivostok
^b Far Eastern Federal University, Vladivostok
^c Institute for Automation and Control Processes, Far Eastern Branch of the Russian Academy of Sciences, Vladivostok

Abstract: Polymer luminescent compositions based on polystyrene (PS), polycarbonate (PC) and polymethyl methacrylate (PMMA) doped with boron difluoride dibenzoylmethanate (DBMBF$_2$), boron difluoride anthracenoylacetonate (AntAcBF$_2$) and their mixture were investigated. Composition based on PS has a maximum quantum yield of luminescence. The role of PS in increasing the efficiency of energy transfer from the donor (DBMBF$_2$) to the acceptor (AntAcBF$_2$) is revealed, which is due to the formation of exciplexes between DBMBF$_2$ and phenyl rings of PS.

Keywords: $\beta$-diketonates boron difluoride, boron difluoride dibenzoylmethanate, polymers, luminescence, exciplexes.

Received: 24.12.2018
Revised: 24.12.2018
Accepted: 07.05.2019

DOI: 10.21883/OS.2019.09.48195.373-18